(6) CH (6) CH3CH2CH2CBr2CH3 (7)CH3CCH2CH3 (6) CH (6) CH3CH2CH2CBr2CH3 (7)CH3CCH2CH3 2. (1)⑵ 2. (1)⑵(5) 4.80*45%/12=3 3fF2 第一章 易溶于水；(3)⑷(6) 难溶于水。 80*7.5%/1=6 80*47.5%/19=2 C 第二章有机化合物的结构本质及构性关系 2 3 2 ⑷sp⑸sp ⑹sp 第四章开链 (1) 2-甲基-4,5-二乙基庚烷 (2) 3- 甲基戊烷 ⑷(顺)-3-甲基-3-己烯or Z-3- 甲基-3-己烯 2. 3 1. (1) sp ⑵ sp ⑶sp 烃 (3) 2,4- 二甲基-3-乙基戊烷 (12) 3- 甲基-1-庚烯-5-炔 CH3 ⑴ ⑴ CH3CH2CHCH(CH2)4CH3 (2) (CH3)2CHCH2CH2CH3 C2H C2H5 CH3 CH3 (3) (CH3 (3) (CH3)2CHC—CH(CH3)2 CH3CH2CH=C(CH2)3CH3 C2H5 C2H5 (CH3)2CHC—CH(CH2)3CH3 H3C H H C C CH2CH2CH3 C2H5 (7)CH2CH3(8)(CH3)2CHC—c-c—CCH(CH (7) CH2CH3 (8) (CH3)2CHC—c-c—CCH(CH3)2 H3C (9) 7. H =C〈H CH3 H5C2 C2H5 (10) C C \o "Current Document" H3C XCH3 ClCl H Cl11. Cl (1) CH3CHCH2CH2CH3 (2) (CH3)2CCH2CH3 Br Br CH3 (3) (CH3)2CCH(CH3)2 (4) CH3CH2CC2H5 1 Br 1 Br (3) CH3CHCH2CH3 12. ⑴(CH3)2CCH2CH3 (2) ch3ch2ch2ch3 OH (4) CH3COOH + (4) CH3COOH + H3C c—o H3CZ (5) CH3CH2CHCH3 OSO3H CH3CH2CHCH3 OH 0 2. 2. 2. 2. Br (8)(CH3)2CCH —CH2 + (CH3)2C_CHCH2Br CH— CH2 (9) (CH2CYHCH2) n + (CH?—C) n Cl Cl (10) I CHO 14. (5) > (3) > (2) > (1) > (4) CH=CHCHCH > (CH3) 3C+ > CHCHKJHCH > CHCHCHKJh〉(CH3) 2CH(CH2 16. (1) 17. 21 即： 1-戊烯 * V溴褪色 Br 2/CCI 4 1-戊炔 卜室温,避光* V溴褪色 戊烷 X 1-丁炔］ V灰白色J Ag(NH 3)2+ 2-丁炔 ? X 丁烷」 X Ag(NH 3)2+ X 1,3-丁 —烯 1-己炔 BH/CCI4 溴褪色 溴褪色 Br2/CCl4 V溴褪色 室温，避光 Ag(NH 3耳 X V灰白色J (2)CH——CH h2o [CH2——CHOH] H2SO4,HgSO4 ■CH3CHO KMnO 4/H 10.( 1) CH-CH=CH CHCOOH (2) CH-gCH+HBr( 2imol) CH QBdCH HBr(1moI) B「2 (3) CH-g CH CH-C=CH CHCBr^CHBr Br 第四章环烃 6 6、 ⑶ (1) ⑵ 3 4 Cl (1) Br Br Cl O2N Br (5) COOH + NO2 (9) (10) 10 6-3 H H Br n H CH CHj CI I CH3 (2) Cl ⑷H3C Cl + (3) X (4) V (5) V (6) V CH3 (3) (CH3)2C CH(CH3)2 C2H5 Br C2H5 (6) (CH3)3C — ?-一COOH ⑺CH3 COCH3 CH3 L COti Br- IC皿忒 —A * 第六章旋光异构 C(CH 3)3 SO3H 7. (2)有芳香性 苯/无水AICI 3 nhcoch3 2. (1) X (2) X (8) 1molCI 2 / h CH3 ch2oh H—OCH3 CIIS CH.OH CHjO (1) .. 7 f CH3 — 反式 Br 顺式 ]CHiC 迟 7. ]20 18.8 D c l 5.678 2、 4、 20 1 66' 白J AgNO 3/乙醇，室温 X 白J > \ AgNO 3/乙醇，加热 一 ? X J X 第七章卤代烃 ￥ (lJCiIhCHBrCIbBr C2IhC =CII C^IIsCCH^ (2)C1CH=CHCH2()CH3
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